Silylated polyurethanes, their preparation and use

US10118984B2 · kind B2 · utility

Assignee

• Henkel AG & Co. KGaA · DE

Inventors

• Ralf Bätzgen · Goldkronach, DE
• Jan-Erik Damke · Goldkronach, DE
• David Briers · Hasselt, BE
• Johann Klein · Goldkronach, DE

Key dates

• Filing date: Sep 7, 2017
• Grant date: Nov 6, 2018
• Expiry date: Sep 7, 2037

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08G18/792
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

A silylated polyurethane obtainable by a process comprising the following steps: (a) reacting at least one polyol with at least one triisocyanate to form a hydroxyl-terminated polyurethane prepolymer, and (b) reacting said polyurethane prepolymer with at least one isocyanatosilane of the formula (1): OCN—R—Si—(X)m(R1)3−m, wherein m is 0, 1 or 2, each R1 is independently from each other a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, an acyloxy group having 1 to 10 carbon atoms, or —OCH(R2)COOR3, wherein R2 is hydrogen or an alkyl group having 1 to 4 carbon atoms and R3 is a straight-chain or branched alkyl group having 1 to 8 carbon atoms, each X is independently from each other and optionally substituted hydrocarbon group having 1 to 10 carbon atoms, which can be interrupted by at least one heteroatom, and R is a difunctional organic group, to endcap the hydroxyl groups on said prepolymer with said isocyanatosilane. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.