Patent · US Active

Backfunctionalized imidazolinium salts and NHC carbene-metal complexes

US10150738B2 · kind B2 · utility

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Key dates

Filing dateMay 16, 2017
Grant dateDec 11, 2018
Priority date
Expiry dateMay 16, 2037

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F15/0046
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Backfunctionalized imidazolinium salts and methods of synthesizing the same and NHC carbene-metal complexes therefrom. For backfunctionalized imidazolinium salts of the formula: Wherein R1 is selected from the group consisting of an ester group, an amide group, and an aromatic group; R2 is selected from the group consisting of hydrogen, an ester group, an amide group, and an aromatic group; R3 and R4 are each an aliphatic group; and X is an anion; the method comprises cyclization of a halogenated acrylate with Hünig's base in a solvent.

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