Patent · US Active

Composite method of trapping carbon dioxide in gas mixture

US10173167B2 · kind B2 · utility

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1References
9Claims
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Key dates

Filing dateJun 5, 2014
Grant dateJan 8, 2019
Priority date
Expiry dateJun 5, 2034

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02C20/40
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A hybrid method for capturing CO2 from a gas mixture is provided, comprising a step of contacting the CO2 containing gas mixture with a slurry consisting of a liquid medium, imidazole or imidazole derivative(s), and a metal-organic framework material (MOFs). For the slurry system, the mass fraction of the imidazole or imidazole derivative(s) in it ranging from 2 to 50% and the mass fraction of the metal-organic framework material in it ranging from 5 to 25%. In the technical solution provided in the present invention, through combining absorptive separation by the liquid solution in which the imidazole or imidazole derivative(s) is dissolved, adsorption separation by the MOF material suspended in the solution, and selective permeation separation by a liquid medium film forms on the outside surface of the suspended MOFs, an absorption-adsorption hybrid separation effect for CO2 gas mixtures is efficiently achieved. In the CO2 capture method provided in the present invention, conventional absorption separation and adsorptive separation technologies are effectively combined, furthermore, the addition of imidazole or imidazole derivative(s) substantially increases both the CO2 capture …

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