Patent · US Active

Methods for controlling polymer properties

US10227428B2 · kind B2 · utility

3Cited by
4References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 25, 2014
Grant dateMar 12, 2019
Priority date
Expiry dateSep 25, 2034

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08L23/08
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Disclosed herein are methods of controlling polymer properties in polymerization processes that use a chromium-based catalyst. An embodiment discloses a method of producing a polyolefin comprising: contacting a reaction mixture and a reduced chromium oxide catalyst in a gas-phase reactor to produce the polyolefin, wherein the reaction mixture comprises a monomer and a co-monomer; and changing a reaction temperature in the gas-phase reactor by about 1° C. or more whereby a gas molar ratio of the co-monomer to the monomer is changed by about 2% or more and a co-monomer content of the polyolefin at substantially constant density is changed by about 2% or more. Additional methods and compositions are also provided.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.