Preparation of titanium catecholate complexes in aqueous solution using titanium tetrachloride or titanium oxychloride
US10253051B2 · kind B2 · utility
Assignees
Inventors
Key dates
| Filing date | Mar 15, 2016 |
| Grant date | Apr 9, 2019 |
| Priority date | — |
| Expiry date | Nov 28, 2036 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/50
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
Titanium coordination complexes, particularly titanium catecholate complexes, can be attractive active materials for use in flow batteries. However, such coordination complexes can be difficult to prepare from inexpensive starting materials, particularly in aqueous solutions. Titanium oxychloride and titanium tetrachloride represent relatively inexpensive titanium sources that can be used for preparing such coordination complexes. Methods for preparing titanium catecholate complexes can include combining one or more catecholate ligands and titanium oxychloride in an aqueous solution, and reacting the one or more catecholate ligands with the titanium oxychloride in the aqueous solution to form the titanium catecholate complex. Titanium tetrachloride can be used as a precursor for forming the titanium oxychloride in situ. In some instances, the titanium catecholate complex can be isolated in a solid form, which can be substantially free of alkali metal ions.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.