Metathesis polymerization methods

US10273327B2 · kind B2 · utility

Assignee

• University of Washington · US

Inventors

• Andrew J. Boydston · Middleton, US
• Kelli Ogawa · Midland, US
• Adam Edward Goetz · Los Angeles, US
• Damian Dunford · Seattle, US
• Laura Marie Murphy Pascual · Seattle, US

Key dates

• Filing date: Sep 3, 2015
• Grant date: Apr 30, 2019
• Expiry date: Oct 13, 2035

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08G2261/80
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

The present disclosure is directed to methods of making a polymer, including exposing a reaction mixture including a strained cyclic unsaturated monomer and an organic initiator to a stimulus to provide an activated organic initiator, whereby the activated organic initiator is effective to polymerize the strained cyclic unsaturated monomer via a 4-membered carbocyclic intermediate to provide a polymer having constitutional units derived from the strained cyclic unsaturated monomer.