Process for dehydration of oxygenates with heteropolyacid catalysts having mixed oxide supports and use of the same
US10407356B2 · kind B2 · utility
Assignee
Inventor
Key dates
| Filing date | Dec 18, 2015 |
| Grant date | Sep 10, 2019 |
| Priority date | — |
| Expiry date | Dec 28, 2035 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/584
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The present invention relates to a process for producing ethene by the vapor phase dehydration of ethanol using a supported heteropolyacid catalyst. In particular, the present invention involves the use of a supported heteropolyacid catalyst, wherein the supported heteropolyacid catalyst is: i) a mixed oxide support comprising silica and a transition metal oxide, wherein silica is present in an amount of at least 50 wt. %, based on the weight of the mixed oxide support; or ii) a mixed oxide support comprising zirconia and a different transition metal oxide, wherein zirconia is present in an amount of at least 50 wt. %, based on the weight of the mixed oxide support. When used in a process for the preparation of ethene by vapor phase dehydration, and after attaining steady-state performance of the catalyst, the process may be operated continuously with the same supported heteropolyacid catalyst for at least 150 hours without any regeneration of the catalyst.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.