Method for one-step synthesis, cross-linking and drying of aerogels
US10414894B2 · kind B2 · utility
Assignee
Inventor
Key dates
| Filing date | Jul 31, 2015 |
| Grant date | Sep 17, 2019 |
| Priority date | — |
| Expiry date | Aug 26, 2035 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/54
- WIPO fieldOther special machines
- WIPO sectorMechanical engineering
Abstract
A method of synthesizing aerogels and cross-linked aerogels in a single step and in a single pot without requiring any solvent exchange is described. Porous matrices are synthesized through a modification of hydrolysis condensation of alkoxides in which addition of water is minimized. The reaction occurs in an ethanol-water azeotrope mixture; the water in the azeotrope slowly hydrolyzes the alkoxide. Additionally, after gelation, the porous matrix is dried in supercritical ethanol rather than liquid CO2, which allows for elimination of solvent exchange steps. These modifications allow for the preparation of aerogel monoliths in any size in one step and in one pot and much faster than conventional procedures. In addition, the method provides for custom aerogel parts with large dimensions, as well as high volume fabrication of aerogels. The custom aerogel parts may be used in a variety of thermal insulation applications.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.