Catalytic effects of oxygen carrier based chemical-looping reforming of CH4 with CO2
US10478807B2 · kind B2 · utility
Inventors
Key dates
| Filing date | May 30, 2017 |
| Grant date | Nov 19, 2019 |
| Priority date | — |
| Expiry date | May 30, 2037 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P30/00
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The invention relates to CeO2 and La2O3 for catalyzing Fe2O3—Al2O3 based chemical-looping reforming of CH4 with CO2 (CL-DRM). The reaction performance of all the composite oxygen carriers was evaluated in a fixed-bed reactor at atmospheric pressure condition. The influencing factors, including temperature and time-on-stream (TOS) were investigated. The characteristics of the oxygen carriers were checked with Brunauer-Emmett-Teller (BET) analysis and X-ray diffraction (XRD). The reducibility of the composite materials was elucidated with temperature-programmed reduction by CH4 (CH4-TPR). Preliminary experimental observations suggest that the simultaneous presence of CeO2 and La2O3 can not only enhance the reactivity of Fe2O3—Al2O3 toward CH4 oxidation and its oxygen releasing rate for fast reaction kinetics, but also improve the reactivity of its reduced form toward CO2 splitting.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.