Patent · US Active

Fluorine substitution influence on benzo[2,1,3]thiodiazole based polymers for field-effect transistor applications

US10487173B2 · kind B2 · utility

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4References
21Claims
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Key dates

Filing dateJun 6, 2018
Grant dateNov 26, 2019
Priority date
Expiry dateJun 6, 2038

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G2261/92
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Four conjugated copolymers with a donor/acceptor architecture including 4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b′]dithiophene as the donor structural unit and benzo[2,1,3]thiodiazole fragments with varying degrees of fluorination have been synthesized and characterized. It has been shown that the HOMO levels were decreased after the fluorine substitution. The field-effect charge carrier mobility was similar for all polymers with less than an order of magnitude difference between different acceptor units.

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