Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins

US10611864B2 · kind B2 · utility

Assignee

• SABIC GLOBAL TECHNOLOGIES B.V. · NL

Inventors

• Martin Alexander Zuideveld · Kelmis, BE
• Jaiprakash Brijlal Sainani · Sayla, IN
• Osamah Al-Humaidan · Riyadh, SA
• Sudhakar R. Padmanabhan · Riyadh, SA
• Prashant Sukumar Shinge · Bengaluru, IN
• Sharankumar G. Shetty · Bengaluru, IN
• Abbas-Alli Ghudubhai Shaikh · Savanuru, IN

Key dates

• Filing date: Sep 22, 2016
• Grant date: Apr 7, 2020
• Expiry date: Dec 20, 2036

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08F2500/18
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

The present invention relates to a compound according to Formula (I) wherein R1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups, and one or more combinations thereof; wherein R2 is a hydrogen atom, an aryl group or an alkyl group; and wherein R3, R4, R5 and R6, are the same or different and are each independently a hydrogen atom, a halogen atom, a cyano group, an amino group, a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups or an alkoxy group, and one or more combinations thereof as internal electron donor and to a process for the synthesis of a compound according to Formula (I), wherein R1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl and alkylaryl groups, and one or more combinations thereof; wherein R2 is a hydrogen atom or an alkyl group; wherein R3, R4, R5 and R6, are the same or different and are each independently selected from a group consisting of a hydrogen atom; a hydrocarbyl, preferably, said process comprising the step of reacting a compound according to Formula (II) [R1—C(═O)Cl] with …