Method for simultaneously removing SO2 and NOX in flue gas
US10814273B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 15, 2019 |
| Grant date | Oct 27, 2020 |
| Priority date | — |
| Expiry date | Oct 15, 2039 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02A50/20
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The invention discloses a method for simultaneously removing SO2 and NOx in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60° C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NOx into ammonium nitrate, and the removal efficiency of the NOx and the SO2 is high.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.