Patent · US Active

Templated synthesis of shape-controlled polymeric nanofibers by chemical vapor deposition (CVD) in liquid crystals

US10907038B2 · kind B2 · utility

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Key dates

Filing dateApr 14, 2017
Grant dateFeb 2, 2021
Priority date
Expiry dateApr 14, 2037

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG02F1/13718
  • WIPO fieldTextile and paper machines
  • WIPO sectorMechanical engineering

Abstract

Methods are provided for fabricating functional nanostructures (e.g., nanowires/nanofibers) via chemical vapor deposition polymerization of paracyclophanes or substituted paracyclophanes onto and through a structured fluid, such as a film of liquid crystals, on a substrate. A one-step process is provided that does not require the use of any solid templates, nor does it require any volatile solvents, additives or catalysts. The resulting nanowires/nanofibers can be in the form of aligned nanowires/nanofibers arrays supported on any solid material, in the form of nanofibers mats supported on porous materials, or as individual free-standing nanowires/nanofibers. By using chiral liquid crystals, chiral nanofibers can be fabricated. The functional nanowires/nanofibers can contain one or more type of surface reactive groups that allows for post surface chemical modifications on the nanowires/nanofibers. Such nanostructures can be used in a range of different applications, including in biomedical applications.

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