Patent · US Active

Method of preparing pH/reduction responsive polyamino acid zwitterionic nanoparticles

US10933028B2 · kind B2 · utility

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9Claims
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Key dates

Filing dateDec 3, 2018
Grant dateMar 2, 2021
Priority date
Expiry dateDec 3, 2038

Classification

  • Technology area (CPC A)Human Necessities
  • CPC primaryA61K31/351
  • WIPO fieldPharmaceuticals
  • WIPO sectorChemistry

Abstract

The invention discloses a preparation method of pH/reduction responsive polyamino acid zwitterionic nanoparticles, which belongs to the technical field of polymer synthesis and biomedical materials. In the invention aliphatic amines are used to initiate ring-opening polymerization of γ-benzyl-L-glutamate-N-carboxylic anhydride, and the obtained poly(γ-benzyl-L-glutamate) reacts with L-lysine to form azwitterionic polymer. The zwitterionic polymer is crosslinked by cysteamine, producing pH/reduction responsive polyamino acid zwitterionic nanoparticles after purification. The nanoparticles are pH responsive and resistant to non-specific protein adsorption. Because cysteamine contains disulfide bonds, the nanoparticles have sensitive reductive responsiveness and can load anticancer drugs for controlled release at the target site of cancer.

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