(Meth)acrylated compounds based on recycled PET
US10941271B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jul 10, 2017 |
| Grant date | Mar 9, 2021 |
| Priority date | — |
| Expiry date | Dec 5, 2037 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02W30/62
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The present invention relates to a process for preparing a polyester (meth)acrylate resin (I), said process comprising the steps of: (a) Reacting a thermoplastic polyester with (a1) at least one polyhydric alcohol and, optionally, with (a2) at least one triglyceride, wherein the molar ratio of triglyceride to thermoplastic polyester is between 0 and 0.3, and the molar ratio of polyhydric alcohol to thermoplastic polyester is at most 1.9 to obtain a depolymerization product A that has a hydroxyl number within the range of from 200 to 800 mg KOH/g; (b) Reacting the depolymerization product A with (b1) at least one fatty acid and/or (b2) at least one polybasic carboxylic acid and, optionally, with (b3) at least one polyhydric alcohol to provide a polyester polyol B; (c) Reacting the polyester polyol B with (c) at least one (meth)acrylating compound to provide a (meth)acrylated compound (I), wherein the weight ratio of fatty acid (b 1) to the depolymerization product A is between 0 and 0.6, wherein the weight ratio of polybasic carboxylic acid (b2) to the depolymerization product A is less than 0.3, wherein the weight ratio of (meth)acrylating compounds (c) to the depolymerization prod…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.