Patent · US Active

Stabilization of active metal catalysts at metal-organic framework nodes for highly efficient organic transformations

US10953393B2 · kind B2 · utility

3Cited by

0References

20Claims

0Family size

Assignee

THE UNIVERSITY OF CHICAGO · US

Inventors

Wenbin Lin · Chicago, US
Kuntal Manna · Chicago, US
Pengfei Ji · Shanghai, CN

Key dates

Filing date	Oct 12, 2016
Grant date	Mar 23, 2021
Priority date	—
Expiry date	Nov 21, 2036

Classification

Technology area (CPC Y)Emerging Cross-Sectional Technologies
CPC primaryY02P20/54
WIPO fieldOrganic fine chemistry
WIPO sectorChemistry

Abstract

Metal-organic framework (MOFs) compositions based on post¬synthetic metalation of secondary building unit (SBU) terminal or bridging OH or OH2 groups with metal precursors or other post-synthetic manipulations are described. The MOFs provide a versatile family of recyclable and reusable single-site solid catalysts for catalyzing a variety of asymmetric organic transformations, including the regioselective boryiation and siiylation of benzyiic C—H bonds, the hydrogenation of aikenes, imines, carbonyls, nitroarenes, and heterocycles, hydroboration, hydrophosphination, and cyclization reactions. The solid catalysts can also be integrated into a flow reactor or a supercritical fluid reactor.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.