Free-standing MOF-derived hybrid porous carbon nanofiber mats
US10998550B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jan 16, 2017 |
| Grant date | May 4, 2021 |
| Priority date | — |
| Expiry date | Dec 8, 2037 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02E60/10
- WIPO fieldTextile and paper machines
- WIPO sectorMechanical engineering
Abstract
According to the present disclosure, a method of fabricating a metal-carbon fibrous structure is provided. The method comprises the steps of: (a) forming a fibrous support structure comprising composite nanocrystals and polymeric fibers, wherein each of the composite nanocrystals comprises metal ions connected by organic ligands; (b) growing the composite nanocrystals on the fibrous support structure; and (c) subjecting the fibrous support structure of step (b) to carbonization to form the metal-carbon fibrous structure, wherein the metal-carbon fibrous structure comprises metal nanoparticles derived from the composite nanocrystals comprising metal organic framework (MOF), particularly zeolitic imidazolate framework (ZIF). A metal-carbon fibrous structure comprising carbon based fibers arranged to form a porous network and the carbon based fibers are doped with metal nanoparticles, wherein the carbon based fibers have surfaces which comprise graphitic carbon, is also disclosed herein.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.