Patent · US Active

Preparation method for hollow molybdate composite microspheres and method for catalyzing ammonia borane hydrolysis to produce hydrogen

US11027259B2 · kind B2 · utility

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Key dates

Filing dateJan 20, 2020
Grant dateJun 8, 2021
Priority date
Expiry dateJan 20, 2040

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02E60/36
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A method of preparing hollow molybdate composite microspheres includes steps of: (1) dissolving 1-4 mmol of MCl2 in 20 ml of water to obtain a solution A and dissolving 1-4 mmol. of molybdic acid in 20 ml of water to obtain a solution B, followed by mixing the solution A and the solution B, in which M is Co, Ni, or Cu; (2) dissolving 10-40 mmol of urea in 40 ml of water, adding the mixed solution of step (1) and stirring uniformly; (3) placing the mixed solution of step (2) into a reaction vessel and reacting at 120-160° C. for 6-12 hours; (4) suction filtrating and water washing, followed by drying in a vacuum oven at 40-60° C.; (5) calcination at 350-500° C. for 2-4 hours in a Muffle furnace.

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