Patent · US Active

Catalyst-containing oxygen transport membrane

US11052353B2 · kind B2 · utility

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175References
18Claims
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Key dates

Filing dateMar 2, 2017
Grant dateJul 6, 2021
Priority date
Expiry dateJun 7, 2037

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC04B2237/765
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A method is described of producing a catalyst-containing composite oxygen ion membrane and a catalyst-containing composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln1−xAx)wCr1−yByO3−δ and a doped zirconia. Adding certain catalyst metals into the fuel oxidation layer not only enhances the initial oxygen flux, but also reduces the degradation rate of the oxygen flux over long-term operation. One of the possible reasons for the improved flux and stability is that the addition of the catalyst metal reduces the chemical reaction between the (Ln1−xAx)wCr1−yByO3−δ and the zirconia phases during membrane fabrication and operation, as indicated by the X-ray diffraction results.

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