Expansion-tolerant three-dimensional (3D) carbon-based structures incorporated into lithium sulfur (Li S) battery electrodes
US11335911B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Aug 20, 2020 |
| Grant date | May 17, 2022 |
| Priority date | — |
| Expiry date | Aug 20, 2040 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P70/50
- WIPO fieldElectrical machinery, apparatus, energy
- WIPO sectorElectrical engineering
Abstract
This disclosure provides an electrode having a carbon-based structure with a plurality of localized reaction sites. An open porous scaffold is defined by the carbon-based structure and can confine an active material in the localized reaction sites. A plurality of engineered failure points is formed throughout the carbon-based structure and can expand in a presence of volumetric expansion associated with polysulfide shuttle. The open porous scaffold can inhibit a formation of interconnecting solid networks of the active material between the localized reaction sites. The plurality of engineered failure points can relax or collapse during an initial activation of the electrode. The open porous scaffold can define a hierarchical porous compliant cellular architecture formed of a plurality of interconnected graphene platelets fused together at substantially orthogonal angles. The hierarchical porous compliant cellular architecture can be expansion-tolerant and can expand in a presence of Li ion insertion or de-insertion.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.