Fluorine-containing alternating copolymer macromonomer and synthesis method thereof
US11365267B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jun 14, 2019 |
| Grant date | Jun 21, 2022 |
| Priority date | — |
| Expiry date | Feb 10, 2040 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F2810/30
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The present invention relates to a fluorine-containing alternating copolymer macromonomer and a synthesis method thereof. The synthesis method comprises steps of: subjecting a fluorine-containing alternating copolymer to a reduction reaction at 60-100° C. in an organic solvent in the presence of a reducing agent and a first catalyst to obtain a reduction product; in the presence of a second catalyst, reacting the reduction product with a mercapto-monohydric alcohol in an organic solvent at 60-100° C., to obtain a hydroxyl-terminated fluorine-containing alternating copolymer; and in the presence of a third catalyst, reacting the hydroxyl-terminated fluorine-containing alternating copolymer with an acrylic monomer or acryloyl chloride monomer at 0-30° C., to obtain the fluorine-containing alternating copolymer macromonomer. In the present invention, a fluorine-containing alternating copolymer macromonomer is initially synthesized from a fluorine-containing alternating copolymer through polymer modification.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.