Method for efficiently separating magnesium and lithium from salt lake brine and simultaneously preparing high-purity magnesium oxide and battery-grade lithium carbonate

US11524901B2 · kind B2 · utility

Assignee

• Beijing University of Chemical Technology · CN

Inventors

• Xu Xiang · Wenzhou City, CN
• Xue Duan · Beijing, CN

Key dates

• Filing date: Mar 8, 2019
• Grant date: Dec 13, 2022
• Expiry date: Apr 22, 2040

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C02F2103/007
• WIPO field: Environmental technology
• WIPO sector: Chemistry

Abstract

This invention provides a method for efficiently separating magnesium and lithium from salt lake brine, and simultaneously preparing high-purity magnesium oxide and battery-grade lithium carbonate. The detailed processing steps are as follows: (1) adding urea into the brine to dissolve, (2) placing the solution into the reactor for hydrothermal reaction, the magnesium ion will precipitate and enter the solid phase; (3) filtering and drying the production to get the magnesium carbonate solid, while the lithium ion remains in the liquid phase; (4) after directly concentration and precipitation, the battery-grade lithium carbonate can be obtained, while the calcination of solid-phase product results in the high-purity magnesium oxide. In this method, urea is used as the precipitant to separate magnesium and lithium in salt lake without introducing any new metal ion, and the brine solution is not diluted. The solid product is white and fluffy powder, which is easy to filter and separate. The extraction rate of lithium is high than 94%, and the purity of MgO obtained by calcination is higher than 99.5%.