Process for producing halogenated olefins
US11731925B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Jul 24, 2017 |
| Grant date | Aug 22, 2023 |
| Priority date | — |
| Expiry date | Sep 21, 2040 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C21/18
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Disclosed herein is a process comprising contacting a haloalkane reactant with an olefin in the presence of a catalyst system that consists of metallic iron and a phosphine to produce a haloalkane insertion product, wherein said haloalkane reactant is an alkane substituted with at least one halogen selected from the group consisting of F, Cl, and combinations thereof. Also disclosed herein is a process comprising contacting CF3CCl3 with CH2═CHX in the presence of a catalyst system that consists of metallic iron and a phosphine to make CF3CCl2CH2CHClX, wherein X═F or Cl. Also disclosed are further reactions in a sequence to produce HFO-1336ze and HCFO-1335zd. Also disclosed herein is a new composition comprising the compound CF3CF2CH═CHCl.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.