Catalyst-free method for degrading dioxane in alkyl ether sulfate vacuum removal water
US11827544B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Dec 9, 2022 |
| Grant date | Nov 28, 2023 |
| Priority date | — |
| Expiry date | Dec 16, 2042 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC02F2305/023
- WIPO fieldEnvironmental technology
- WIPO sectorChemistry
Abstract
A method of degrading 1,4-dioxane in the wastewater produced during the manufacture of alkyl ether sulfates is disclosed. The method includes the steps of (a) mixing from 100 to 10,000 ppm, preferably 1,000 to 4,000 ppm of ozone with the wastewater; (b) introducing H2O2 into the wastewater in an amount of 0.01 to 10, preferably 0.1 to 0.5 molar equivalents of H2O2 to ozone, and (c) mixing the ozone, H2O2, and wastewater to generate hydroxyl radicals reactive with the 1,4-dioxane, without the addition of a metal catalyst. The hydroxyl radicals react with the 1,4-dioxane and degrade it into carbon dioxide, water and/or carbonate. The method is effective to reduce a concentration of 1,4-dioxane in the wastewater from a range of about 10 ppm to about 1000 ppm of dioxane down to less than 5 ppb of 1,4-dioxane after treatment. The method is also effective for removing hydrocarbon species that may be present in the wastewater.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.