Phosphorus-containing rare-earth-containing MFI structure molecular sieve rich in mesopore, preparation method, and catalyst containing same and application thereof

US11964262B2 · kind B2 · utility

Assignees

• CHINA PETROLEUM & CHEMICAL CORPORATION · CN
• RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC · CN

Inventors

• Ying Ouyang · Beijing, CN
• Yibin Luo · Beijing, CN
• Jianqiang Liu · Campbell, US
• Li Zhuang · Beijing, CN
• Minggang Li · Beijing, CN
• Xingtian Shu · Beijing, CN

Key dates

• Filing date: Oct 17, 2019
• Grant date: Apr 23, 2024
• Expiry date: Jul 24, 2040

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y02P20/52
• WIPO field: Chemical engineering
• WIPO sector: Chemistry

Abstract

A rare earth- and phosphorus-containing molecular sieve of MFI structure rich in mesopores has a ratio of n(SiO2)/n(Al2O3) of more than 15 and less than 70. The molecular sieve has a content of phosphorus of 1-15 wt %, calculated as P2O5 and based on the dry weight of the molecular sieve. The content of the supported metal in the molecular sieve is 1-10 wt % supported metal M1 and 0.1-5 wt % supported metal M2 based on the oxide of the supported metal and the dry weight of the molecular sieve. The supported metal M1 is one or two selected from lanthanum and cerium, and the supported metal M2 is one selected from iron, cobalt, nickel, copper, manganese, zinc, tin, bismuth and gallium; the volume of mesopores in the molecular sieve represents 40-70% by volume of the total pore volume of the molecular sieve by volume.