Polyol blends and rigid foams with improved low-temperature R-values
US11993708B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Oct 9, 2020 |
| Grant date | May 28, 2024 |
| Priority date | — |
| Expiry date | Dec 9, 2040 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08L2205/03
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Blends comprising an aromatic polyester polyol and a 1 to 10 wt. % of a fatty acid derivative are disclosed. The fatty acid derivative is a C8 to C18 fatty acid ester or a C8 to C18 fatty acid amide. Also disclosed are rigid PU or PU-PIR foams that comprise a reaction product of water, a catalyst, a foam-stabilizing surfactant, a polyisocyanate, a blowing agent, and the polyester polyol/fatty acid derivative blends. Surprisingly, low-temperature R-values of rigid foams based on pentane blowing agents can be improved significantly by using blends of aromatic polyester polyols and a minor proportion of readily available fatty acid derivatives. In some aspects, the difference between initial R-values of the foam measured at 75° F. and 40° F. is at least 5% greater than that of a similar foam prepared in the absence of the fatty acid derivative.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.