Patent · US Active

Method for producing dicarboxylic acid

US11999688B2 · kind B2 · utility

0Cited by
3References
12Claims
0Family size

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Inventors

Key dates

Filing dateJun 28, 2018
Grant dateJun 4, 2024
Priority date
Expiry dateJun 22, 2040

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2601/18
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A method for producing dicarboxylic acid. The method includes: subjecting a raw material system including a cyclic olefin and a lower monocarboxylic acid to an addition reaction in the presence of an addition reaction catalyst to generate an intermediate product system including cyclic carboxylic acid ester; and subjecting the intermediate product system including cyclic carboxylic acid ester to a ring-opening and oxidation reaction in the presence of an oxidant and an oxidation catalyst to generate a corresponding dicarboxylic acid product. The addition reaction in the dicarboxylic acid synthesis route achieves a high single-pass conversion rate, and the selectivity of the corresponding cyclic carboxylic acid ester is high. The addition-oxidation synthesis route achieves faster reaction rates for both the addition reaction and oxidation reaction, and high yield of corresponding dicarboxylic acid product. The addition-oxidation based synthesis route is suitable for continuous, stable and large-scale production of corresponding dicarboxylic acid product.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.