Patent · US Active

Seeded solid-phase crystallization of transparent conducting vanadate perovskites

US12074235B2 · kind B2 · utility

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Key dates

Filing dateSep 9, 2020
Grant dateAug 27, 2024
Priority date
Expiry dateJun 29, 2043

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC30B29/30
  • WIPO fieldSurface technology, coating
  • WIPO sectorChemistry

Abstract

Transparent, electrically conductive vanadium oxide-based perovskite films and methods of making the vanadium oxide-based perovskite films are provided. Transparent conducting vanadate perovskites are made by forming a layer of amorphous vanadate perovskite precursor around a plurality of nanoscale, crystalline, perovskite oxide seeds and heating the layer of amorphous vanadate perovskite precursor at a temperature that favors lateral vanadate perovskite crystal growth from the perovskite oxide seeds over homogeneous crystal nucleation within the layer of amorphous vanadate perovskite precursor material. The crystallization processes can form the desired vanadate perovskite phase directly or via a transformation in a controlled gas environment from an initial crystallized vanadate perovskite phase that has a higher oxidation state.

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