Cross-linked high stable anion exchange blend membranes with polyethyleneglycols as hydrophilic membrane phase

US12083511B2 · kind B2 · utility

Inventor

• Jochen Kerres · Esslingen am Neckar, DE

Key dates

• Filing date: Mar 21, 2022
• Grant date: Sep 10, 2024
• Expiry date: Mar 21, 2042

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y02E60/50
• WIPO field: Chemical engineering
• WIPO sector: Chemistry

Abstract

The invention relates to:—anion exchange blend membranes consisting the following blend components:—a halomethylated polymer (a polymer with —(CH2)x—CH2—Hal groups, Hal=F, Cl, Br, I; x=0-12), which is quaternised with a tertiary or a n-alkylated/n-arylated imidazole, an N-alkylated/N-arylated benzimidazole or an N-alkylated/N-arylated pyrazol to form an anion exchanger polymer. - an inert matrix polymer in which the anion exchange polymer is embedded and which is optionally covalently crosslinked with the halomethylated precursor of the anion exchanger polymer,—a polyethyleneglycol with epoxide or halomethyl terminal groups which are anchored by reacting with N—H-groups of the base matrix polymer using convalent cross-linking—optionally an acidic polymer which forms with the anion-exchanger polymer an ionic cross-linking (negative bound ions of the acidic polymer forming ionic cross-linking positions relative to the positive cations of the anion-exchanger polymer)—optionally a sulphonated polymer (polymer with sulphate groups —SO2Me, Me=any cation), which forms with the halomethyl groups of the halomethylated polymer convalent crosslinking bridges with sulfinate S-alkylation. The i…