Two-dimensional polymers comprised of a combination of stiff and compliant molecular units

US12110367B2 · kind B2 · utility

Assignee

• The United States of America as represented by the Secretary of the Army · US

Inventors

• Eric D. Wetzel · Baltimore, US
• Emil Jose Sandoz-Rosado · Baltimore, US
• Todd David Beaudet · Aberdeen, US
• Radhakrishnan Balu · Columbia, US
• John Joseph La Scala · Wilmington, US
• Dominika Nini Lastovickova · Aberdeen, US

Key dates

• Filing date: Jan 16, 2020
• Grant date: Oct 8, 2024
• Expiry date: Jan 16, 2040

Classification

• Technology area (CPC F): Mechanical Engineering; Lighting; Heating
• CPC primary: F41H5/08
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

A family of new and novel molecules for mechanically superior two-dimensional (2D) polymers is described herein. By combining stiff carbon-containing cyclic polymer nodal units with more compliant linear polymer bridge units in an ordered, 2D repeating molecular structure it is possible to tailor the mechanical properties of 2D polymers and their assemblies to provide high stiffness, strength, and toughness. Furthermore, the inherent dimensionality of 2D polymers and their ability to be stacked into ordered and chemically interactive ensembles gives them inherent benefits in a variety of barrier and structural applications over current stiff and strong linear polymer technologies.