Patent · US Active

Method of identifying tobacco carbonyl components using non-targeted mass spectrometry

US12131893B1 · kind B1 · utility

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20Claims
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Key dates

Filing dateOct 30, 2023
Grant dateOct 29, 2024
Priority date
Expiry dateOct 30, 2043

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG16C20/30
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

A method of identifying tobacco carbonyl components using non-targeted mass spectrometry is disclosed, which includes the following steps: (1) preparing a tobacco sample extract; (2) derivatizing (part of) the sample/extract with 2,4-dinitrophenylhydrazine (DNPH); (3) derivatizing (another part of) the sample/extract with DNPH-d3; (4) mixing the derivatized tobacco samples; (5) preparing blank samples; (6) performing ultra performance liquid chromatography (UPLC) and ion trap (Orbitrap) high resolution mass spectrometry (HRMS) on the (derivatized) tobacco samples; (7) processing the LC-MS data; (8) filtering the mass spectrometric characteristic data to retain final chromatographic peaks; and (9) structurally annotating or identifying the retained final chromatographic peaks to obtain the tobacco carbonyl components. The method quickly removes noise or interfering components in the original data set by multiple filtering of the mass spectrometry characteristic data, and enables obtaining composition information of aldehyde and ketone chemical components in cigarettes.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.