Process for producing 4,4′-dichlorodiphenyl sulfoxide

US12168642B2 · kind B2 · utility

Assignee

• BASF SE

Inventors

• Jun Gao · Mountain View, US
• Indre Thiel · Ludwigshafen am Rhein, DE
• Christian SCHUETZ · Ludwigshafen am Rhein, DE
• Lukas METZGER · Ludwigshafen am Rhein, DE
• Oliver Bey · Niederkirchen, DE
• Stefan Blei · Mannheim, DE

Key dates

• Filing date: Feb 6, 2020
• Grant date: Dec 17, 2024
• Expiry date: Jun 15, 2041

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07C315/06
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

The invention relates to a process for producing 4,4′-dichlorodiphenyl sulfoxide comprising: (I) reacting thionyl chloride, chlorobenzene and aluminum chloride in a molar ratio of thionyl chloride:chlorobenzene:aluminum chloride of 1:(6 to 9):(1 to 1.5) at a temperature in the range from 0 to below 20° C., forming an intermediate reaction product and hydrogen chloride; (II) mixing aqueous hydrochloric acid and the intermediate reaction product at a temperature in the range from 70 to 110° C. to obtain an organic phase comprising 4,4′-dichlorodiphenyl sulfoxide and an aqueous phase; (III) cooling the organic phase comprising the 4,4′-dichlorodiphenyl sulfoxide to a temperature below the saturation point of 4,4′-dichlorodiphenyl sulfoxide to obtain a suspension comprising crystallized 4,4′-dichlorodiphenyl sulfoxide; (IV) solid-liquid-separation of the suspension to obtain a residual moisture containing solid 4,4′-dichlorodiphenyl sulfoxide comprising crystallized 4,4′-dichlorodiphenyl sulfoxide and mother liquor.