Electrosynthesis of oxiranes
US12291794B2 · kind B2 · utility
Assignee
Inventors
Key dates
| Filing date | Mar 18, 2021 |
| Grant date | May 6, 2025 |
| Priority date | — |
| Expiry date | Mar 18, 2041 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldSurface technology, coating
- WIPO sectorChemistry
Abstract
Electrosynthesis of oxirane can include contacting a halide electrolyte with an anode and cathode respectively located in anodic and cathodic compartments; supplying olefin reactants into the electrolyte in the anodic compartment, such that the anode generates ethylene chlorohydrin; withdrawing a loaded anodic solution comprising ethylene halohydrin from the anodic compartment, and a loaded cathodic solution comprising OH− ions from the cathodic compartment; and mixing the loaded anodic solution with the loaded cathodic solution under conditions to react ethylene halohydrin with OH— to produce oxirane. The electrocatalyst can include iridium oxide on a titanium substrate, with the iridium oxide provided as nanoparticles on a titanium mesh, and the electrolyte can be aqueous KCl. The electrocatalyst can define an extended heterogenous:homogenous interface with halide ions acting as a reservoir for positive charges, thereby storing and redistributing positive charges to promote selective generation of ethylene halohydrins.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.