Patent · US Active

Ordered cross-stacked metal oxide nanowire array material and preparation method thereof

US12304812B2 · kind B2 · utility

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Key dates

Filing dateMar 9, 2020
Grant dateMay 20, 2025
Priority date
Expiry dateApr 18, 2042

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01P2004/16
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

A method for preparing an ordered cross-stacked metal oxide nanowire array is provided. The method includes the following steps: conducting synthesis by using an amphiphilic diblock copolymer as a structure directing agent, tetrahydrofuran (THF) as a solvent and polyoxometalates (POMs) as an inorganic precursor, where the diblock copolymer can interact with POMs via an electrostatic force to form a core-shell cylindrical micelle in the solvent, which self-assembles to form an ordered multilayer-crossed organic-inorganic composite nanostructure during an evaporation process; the template is removed by calcination in air, thereby obtaining ordered and crossed metal oxide nanowires with various elements doping. The nanowire array material has a high specific surface area, a high crystallinity, and realizes uniform doping of heteroatoms.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.