Patent · US Active

Method for producing calcium sulfate hemihydrate whiskers by using fermentation broth for producing lactic acid with calcium salt method as raw material and synchronously recovering lactic acid monomer

US12319585B2 · kind B2 · utility

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9Claims
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Key dates

Filing dateFeb 3, 2021
Grant dateJun 3, 2025
Priority date
Expiry dateMay 24, 2041

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC12P7/56
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The disclosure discloses a method for producing α-calcium sulfate hemihydrate whiskers by using fermentation broth for producing lactic acid with a calcium salt method as a raw material and synchronously recovering a lactic acid monomer. The method comprises the following steps: 1) after fermentation of lactic acid is ended, heating fermentation broth; 2) stirring, and adding sulfuric acid for reaction; 3) after the reaction is ended, filtering and collecting a solid part, namely α-calcium sulfite hemihydrate whiskers, and collecting a liquid part, namely a free lactic acid solution containing the lactic acid monomer; and 4) washing and drying the obtained α-calcium sulfate hemihydrate whiskers to obtain a α-calcium sulfate hemihydrate whisker finished product, filtering and concentrating the obtained free lactic acid solution to obtain a lactic acid crude product, and refining the lactic acid crude product to obtain a high-purity lactic acid monomer. The disclosure can replace the efficient separation of lactic acid in production of lactic acid with the existing calcium salt method and high value-added transformation of a calcium sulfite byproduct, thereby significantly reducing t…

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