Patent · US Active

Aldehyde byproduct reduction in acrylic acid production using highly active and elective catalysts

US12331014B2 · kind B2 · utility

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6Claims
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Key dates

Filing dateApr 20, 2020
Grant dateJun 17, 2025
Priority date
Expiry dateFeb 27, 2042

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J2523/64
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A catalyst composition comprises an acrolein-oxidizing catalyst comprising a mixed metal oxide catalyst of general formula (1): MoVaA1bA2cA3dOm  (I) in which A1 comprises at least one element selected from the group consisting of W and Cu; A2 comprises at least one element selected from the group consisting of Sb, Fe, and Nb; A3 comprises at least one element selected from the group consisting of Y, Ti, Zr, Hf, Ta, Cr, Mn, Re, Ru, Co, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, B, Al, Ga, In, Ge, Sn, Si, Te, Pb, P, As, Bi, Se, rare earth elements, alkaline elements, and alkaline earth elements; a ranges from 0.01 to 1.0; b ranges from 0.01 to 1.5; c ranges from 0 to 1.5; d ranges from 0 to 1.0; and m is dependent on the oxidation state of the other elements. The catalyst composition further comprises a finishing catalyst comprising a mixed metal oxide catalyst of general formula (II): MoVwNbxX1yX2zOn  (II) in which X1 comprises at least one element selected from the group consisting of Te and Sb; X2 comprises at least one an element selected from the group consisting of Y, Ti, Zr, Hf, Nb, Ta, Cr, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Ag, Au, Zn, B, Al, Ga, In, Ge, Sn, Pb, P, As, Bi, Se, rare…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.