Patent · US Active

Plasticizer-inclusive polymeric-inorganic hybrid layer for a lithium anode in a lithium-sulfur battery

US12418027B2 · kind B2 · utility

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29References
5Claims
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Key dates

Filing dateFeb 16, 2022
Grant dateSep 16, 2025
Priority date
Expiry dateJul 20, 2044

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02E60/10
  • WIPO fieldElectrical machinery, apparatus, energy
  • WIPO sectorElectrical engineering

Abstract

A lithium-sulfur battery including an anode structure, a cathode, a separator, and an electrolyte is provided. A protective layer may form within the anode structure responsive to operational discharge-charge cycling of the lithium-sulfur battery. The protective layer may include a polymeric backbone chain formed of interconnected carbon atoms collectively defining a segmental motion of the protective layer. Additional polymeric chains may be cross-linked to one another and at least some carbon atoms of the polymeric backbone chain. Each additional polymeric chain may be formed of interconnected monomer units. A plasticizer may be dispersed throughout the protective layer without covalently bonding to the polymeric backbone chain. The plasticizer may separate adjacent monomer units of at least some additional polymeric chains. Increasing separation of adjacent monomer units increases a cooperative segmental mobility of the additional polymeric chains and ionic conductivity of the protective layer.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.