Exceptionally rigid and tough ultrahigh molecular weight linear polyethylene

US3944536A · kind A · utility

Assignee

• E.I. DU PONT DE NEMOURS AND COMPANY · US

Inventors

• John Lupton · Schwanau, DE
• James Williams Regester · Chester, US

Key dates

• Filing date: Jun 18, 1973
• Grant date: Mar 16, 1976
• Expiry date: Jun 18, 1993

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10T428/2913
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

Linear ultrahigh molecular weight polyethylene exhibiting a unique combination of rigidity and toughness and the process for the preparation thereof comprising inducing crystallization of the molten polyethylene at temperatures in the range of about 150.degree. to about 270.degree.C. by rapidly increasing the pressure applied from an initial level of about 1 to about 1000 atmospheres or more depending on temperature to a second level of about 2000-7000 atmospheres and higher and then cooling rapidly while maintaining a pressure sufficient to maintain the linear polyethylene in the solid phase until the temperature is below the crystalline melting point of linear polyethylene at atmospheric pressure. The resulting rigid, tough linear ultrahigh molecular weight polyethylene having a crystalline melting point of 142.degree. to 148.degree.C. at atmospheric pressure, as measured by differential thermal analysis, and by the absence of detectable low-angle X-ray scattering peaks indicative of crystalline spacings in the range of 50 A to 2000 A and by the presence of a predominance of fold spacings of about 10,000 A as determined by electron microscopy, and further characterized by exhibit…