Patent · US Expired

Preparation of N-phosphonomethylglycine

US3956370A · kind A · utility

37Cited by
3References
3Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 2, 1973
Grant dateMay 11, 1976
Priority date
Expiry dateJul 2, 1993

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F9/3813
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process of preparing the herbicide N-phosphonomethylglycine which comprises reacting an N-substituted glycine derivative of the formula: ##EQU1## wherein R.sup.1 is a hydrogen atom or an esterifying group, Ar is an aryl radical, and R.sup.2 and R.sup.3 each stand for a hydrogen atom or an aryl radical, with formaldehyde and phosphorous acid in an acidic aqueous medium to give an N-substituted N-phosphonomethylglycine derivative of the formula: ##EQU2## and thereafter reacting the said N-substituted N-phosphonomethylglycine with hydrobromic or hydriodic acid to remove the N-substituent, and recovering N-phosphonomethylglycine.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.