Process for the production of water-adsorbing but water-insoluble cellulose ethers
US3965091A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Nov 18, 1974 |
| Grant date | Jun 22, 1976 |
| Priority date | — |
| Expiry date | Nov 18, 1994 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08B11/193
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
This invention relates to an improvement in the process for the production of water-adsorbing, but largely water-insoluble, cellulose ethers, in which cellulose is alkalized in the presence of alkali and isopropanol as a reaction medium and is so reacted with an etherification agent that by etherification only a water-soluble cellulose ether is produced, and in which process a modification agent which is able to react with the still free hydroxyl groups of the cellulose anhydro glucose groups in an alkaline reaction medium is reacted before, during, or after the etherification, the improvement comprising effecting the etherification of cellulose to carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, hydroxyethyl cellulose, or methylhydroxyethyl cellulose, reacting with the modification agent in the presence of 0.8 to 7.5 parts by weight of isopropanol, based upon the cellulose weight, and employing a modification agent being one of the formulae ##EQU1## R.sub.1 in formula I being hydroxyl, or an acylamino or etherified carbamino group, and R.sub.2 in formula I being hydrogen or a carboxyl group.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.