Method of preparing stable condensation products and products formed by the process
US3965217A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Aug 5, 1974 |
| Grant date | Jun 22, 1976 |
| Priority date | — |
| Expiry date | Aug 5, 1994 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08J2485/00
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Stabilized products which are phosphorus containing oligomers having ##EQU1## linkages between phosphorus atoms and which are obtained by the self-condensation of .beta.-haloalkyl esters of pentavalent phosphorus acids or the condensation products of these esters with an alkyl ester of a pentavalent phosphorus acid are formed by terminating the condensation reaction when it is about 35-75% complete, said condensation being performed in the absence of a nucleophilic initiator, such as a sodium salt initiator. The lower degree of condensation in the product and the absence of the nucleophilic initiator during the condensation reaction, is responsible for the lesser degree of scorching in a polyurethane foam containing the product as compared to one which is formed by allowing the condensation reaction go to completion or by use of a nucleophilic initiator during the condensation. If desired, the final product can be post-treated with an alkylene oxide and/or water or alcohol or by extraction with an inert organic solvent.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.