Patent · US Expired

Method for producing cyclohexene by dehydration of cyclohexanol

US3974232A · kind A · utility

1Cited by
8References
13Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 24, 1975
Grant dateAug 10, 1976
Priority date
Expiry dateJun 24, 1995

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C2601/16
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Cyclohexanol is dehydrated to cyclohexene by heating it in the presence of a heteropolyacid catalyst. The heteropolyacid is selected from tungstophosphoric acid, tungstosilicic acid, molybdophosphoric acid and molybdosilicic acid. Tungstophosphoric acid can be improved in its catalytic performance by calcination. The dehydration reaction is preferably carried out in liquid phase continuously removing cyclohexene by distillation.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.