Patent · US Expired

Block copolymers

US3979479A · kind A · utility

6Cited by
2References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 16, 1974
Grant dateSep 7, 1976
Priority date
Expiry dateDec 16, 1994

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08G69/44
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A novel block copolymer HO--D--A--B--D--H, wherein PA1 A is a polylactonic block of recurring units ##EQU1## B is a polylactamic block of recurring units ##EQU2## C is a polyoxymethylene block of recurring units EQU --CH.sub.2 O-- is prepared by catalytic polymerization of at least one lactone ##EQU3## with at least one lactam ##EQU4## wherein: PM.sub.1 and PM.sub.2 are polymethylene linear chains having from 2 to 13 and 3 to 13 carbon atoms, respectively, and being either non-substituted or having at least one hydrogen atom replaced by an alkyl, aryl, alkylaryl or cycloalkyl radical, and reaction of the resulting A-B copolymer with monomeric formaldehyde. The block copolymer HO--D--A--B--D--H having a preponderant percentage in blocks A, B or D, respectively, behaves as a polylactone, polylactam or polyformaldehyde, respectively, having improved properties.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.