Patent · US Expired

1,2,3,4 Tetrakis-(perfluoroalkyl)-1,3-butadienes

US3983179A · kind A · utility

2Cited by
3References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJan 28, 1975
Grant dateSep 28, 1976
Priority date
Expiry dateJan 28, 1995

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C17/281
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A polyfluorinated butadiene having the formula ##EQU1## wherein n and m are integers from 1 to 10 and n=m or n.noteq.m, is prepared by reductive coupling, exemplarily with copper, of the corresponding 1,2-bis(perfluoroalkyl)iodoethylene having the formula CF.sub.3 (CF.sub.2).sub.n CH = CI--(CF.sub.2).sub.m CF.sub.3. This iodoethylene is conveniently prepared by a simple addition reaction between a perfluoroalkyl iodide and a perfluoroalkyl acetylene. The perfluoralkylated butadienes are useful as transporters of dissolved gas, particularly of oxygen as in blood substitutes.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.