ABS moulding compositions

US4009227A · kind A · utility

Assignee

• BAYER HEALTHCARE LLC · DE

Inventors

• Karl-Heinz Ott
• Harry Rohr · Frechen, DE
• Gert Humme
• Leo Morbitzer

Key dates

• Filing date: Apr 22, 1975
• Grant date: Feb 22, 1977
• Expiry date: Apr 22, 1995

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08L55/02
• WIPO field: Macromolecular chemistry, polymers
• WIPO sector: Chemistry

Abstract

Moulding compositions based on ABS-graft polymers, containing: PA0 A. 5 to 70 parts, by weight of a graft polymer obtained by grafting 20 to 60 parts by weight of a mixture of styrene and acrylonitrile in a ratio, by weight, of 95 : 5 to 60 : 40 onto 80 to 40 parts, by weight, of polybutadiene or a butadiene copolymer with a butadiene content of > 30% with an average particle diameter of 0.26 to 0.65 .mu. and a grafting degree of 0.15 to 0.7; PA0 B. 0 to 50 parts, by weight, of a graft polymer obtained by polymerizing 40 to 60 parts, by weight, of a mixture of styrene and acrylonitrile in a ratio, by weight, of 95 : 5 to 60 : 40 onto 60 to 40 parts, by weight, of polybutadiene or a butadiene copolymer with a butadiene content of more than 30%, with an average particle diameter of from 0.05 to 0.25 .mu. and a grafting degree of 0.4 to 0.9; and PA0 C. 25 to 95 parts, by weight, of a copolymer of styrene and/or .alpha.-methyl styrene on the one hand and acrylonitrile on the other hand in a ratio by weight, of 80 : 20 to 60 : 40 with an average molecular weight M.sub.w (weight average) of from 50,000 to 200,000 and a molecular heterogeneity U of 4.5 to 1.0; such that PA0 D. the ratios,…