Patent · US Expired

Cracking of mixtures containing hydroxyesters

US4012424A · kind A · utility

5Cited by
1References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 7, 1975
Grant dateMar 15, 1977
Priority date
Expiry dateAug 7, 1995

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07D301/02
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

This invention concerns the preparation of oxirane compounds by the vapor phase cracking of hydroxyesters in the presence of a basic material. Specifically, it has been discovered that the aforesaid reaction may be carried out without the prior separation of vicinal glycols, vicinal diesters or both. This is particularly advantageous because vicinal hydroxyesters are frequently formed in combination with these latter materials and the separation thereof is most difficult. Preferably, mixtures of the hydroxyesters, glycols and diesters are first hydrolyzed or esterified in order to increase the hydroxyester content.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.