Thermal transformation of metal chlorides to oxides in a fluidized bed

US4049788A · kind A · utility

Assignee

• Metallgesellschaft AG · DE

Inventors

• Herbert Bierbach
• Heinz Dittmar
• Ernst Heinz · Hamburg, DE
• Klaus Hohmann · Hofheim, DE
• Rolf Rennhack

Key dates

• Filing date: Oct 17, 1975
• Grant date: Sep 20, 1977
• Expiry date: Oct 17, 1995

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10S423/16
• WIPO field: Materials, metallurgy
• WIPO sector: Chemistry

Abstract

A process for the thermal decomposition and conversion of metal chlorides to metal oxides in a fluidized bed wherein the fluidizing gas contains oxygen and the reaction temperature is maintained above the thermal decomposition temperature of the metal chloride but below the sintering temperature of the metal oxide thus produced. The gas velocity is determined by the critical relationship 0.34.rho..sup.0.9 .ltoreq. W.sub.G .ltoreq. 0.56.rho..sup.0.9 where W.sub.G is the approximate gas velocity through the fluidized bed chamber in the absence of the bed and .rho. is the density of the pure fluidized-bedmaterial (metal oxide). The height of the bed is also critical and should be that at which a critical pressure drop of 1200 to 2400 mm (water column) is obtained but at least 350 mm, measuring with the static or settled bed (nonfluidized).