Patent · US Expired

Alkali metal catalyst recovery system

US4057512A · kind A · utility

62Cited by
14References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 29, 1975
Grant dateNov 8, 1977
Priority date
Expiry dateSep 29, 1995

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/584
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

In a coal gasification operation or similar process carried out in the presence of an alkali metal-containing catalyst wherein spent solids containing ash and alkali metal catalyst residues are produced, alkali metal constituents are recovered from the spent solids by first removing magnetic constituents from the solids, contacting the solid particles from which magnetic constituents have been separated with an acid solution to extract alkali metal constituents from the solids and produce a spent acid solution enriched in alkali metal salts, raising the pH of the enriched solution sufficiently to precipitate aluminum from the solution as aluminum hydroxide, heating the remaining solution to precipitate silicon compounds, and recovering an enriched alkali metal solution from which aluminum and silicon compounds have been removed. This process permits the effective recovery of alkali metal catalyst constituents, eliminates iron compounds and other inactive constituents which may otherwise tend to build up in the catalyst system, and makes possible the recovery of aluminum as a valuable by-product of the process.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.