Process for preparing cis-olefins

US4057593A · kind A · utility

Assignee

• Hoechst GmbH · DE

Inventors

• Hans Jurgen Bestmann · Erlangen, DE
• Werner Stransky · Gau-Algesheim, DE
• Otto Vostrowsky · Uttenreuth, DE

Key dates

• Filing date: Mar 29, 1976
• Grant date: Nov 8, 1977
• Expiry date: Mar 29, 1996

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C07B2200/09
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

A process for preparing cis-olefins of the formula ##STR1## where R is alkyl or alkenyl and R.sup.1 is alkyl and alkenyl, both optionally substituted by hydroxy, carbalkoxy or acyloxy, which comprises an ylide solution of the compound R--CH.sub.2 --P.sup.+ (C.sub.6 H.sub.5).sub.3 Br.sup.- in hexaalkyl phosphoric acid triamide and adding an aldehyde of the formula R.sup.1 --CHO.