Method of preparing cerium and terbium activated aluminate phosphors
US4096088A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 7, 1977 |
| Grant date | Jun 20, 1978 |
| Priority date | — |
| Expiry date | Feb 7, 1997 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC09K11/7774
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
Phosphors having useful flourescent emission properties comprise aluminates of magnesium, zinc and/or lithium having an hexagonal or so-called ".beta.-alumina" crystal structure and activated by cerium and terbium. In preferred phosphors the ratio of Mg:Al is from 0.01 to 0.5:1, Ce:Al from 0.001 to 0.1:1 and Tb:Al from 0.005:1 to 0.25:1. Where zinc or lithium wholly or partially replace the magnesium, chemically equivalent amounts may be used. A particuarly useful phosphor conforms substantially to the approximate formula (Ce,Tb).sub.1 Mg.sub.1-2 Al.sub.22 O.sub.x, where x is the number of atoms of oxygen required to satisfy the valencies of the metals. The invention also provides a valuable process for the preparation of such aluminate phosphors, giving a product of fine grain which may not require milling or other severe grinding (which is expensive and tends to harm emission properties) to bring it into the preferred particle size range for lamp manufacture. In this process the source of alumina is aluminium ammonium sulphate (ammonium alum) and this is mixed with oxides of the other constituent metals (or decomposable compounds thereof) and fired at temperatures above 1200.degr…
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